That error means there's another extension on your site that's using a model called "Config" but not loading using the proper Joomla method which inserts the name of the extension first. A model is what interfaces with the database. Our config model is called:
JFBConnectModelConfig
We've run into issues with other extensions in the past that try to load their model simply using the name "Config", which will cause conflicts with any other extension that uses that name, like JFBConnect.
This would also explain the white page. When JFBConnect goes first, we load the config model and cause the 'other' extension to show a white page. When they are ordered first, JFBConnect has issues.
You'll need to narrow down what plugin (or plugins) are instantiating their model the wrong way. It's very likely that it would be a system plugin. What I'd recommend is going to the Plugin Manager and
* Disable plugins one-by-one.
* Test the saving to see if you get the error.
* If so, continue disabling plugins until the error goes away
* When the error goes away, start enabling plugins until you isolate the specific plugin (or plugins) that cause the issue.
If it's caused by multiple plugins, it's likely they'd all be from the same extension, like the dd plugins you have. I don't know what that is, but there were many plugins that started with dd. It's possible that only when all of those plugins (or another group of plugins from a separate extension) are disabled that the error will go away.
If error reporting worked on your site, things would be much easier as the white page would display an error from the specific extension, but the Error Reporting setting in the Joomla Global Configuration area has no effect, which means either the host has disabled that ability or another extension is specifically turning off error reporting (which is really bad).
Once you narrow that down, we'll be able to help further.
I hope that helps,
Alex