The behavior in JFBConnect for this is different depending on whether the social network returns an email address or not.
* For Twitter, an email address is not provided. When the Twitter login button is clicked, the user is brought to JFBConnect's login / register page. On this page there are two forms. The form with the following text "If you already have an account, just log in here, and we'll link your Twitter account to it." allows the user to link an existing account (the one created with Facebook) to the Twitter account. To do this, simply click the Facebook button on that form (or login with the associated Joomla credentials that were created with the first account). The accounts should be linked at this point
* For other networks that return the email, if the email address on the second account (Twitter) matches the email address on the first (Facebook), the two accounts should automatically be linked. If the email addresses do not match, whether the user gets directed to the login / register page to link the accounts like above will depend on your 'Enable Automatic Registration' setting.
I hope this addresses your problem, but let us know if you have any more questions.
-Melissa