To see the login credentials again, you have to remove the application from your Facebook account. In Facebook.com, go to Account Settings -> Apps, and then click the 'x' next to your application. That will force the credential check again (even if you don't delete the user from Joomla first).
As for future credentials.. if you add a profile plugin and import info from their profile, it will most likely require a new permissions confirmation when the user tries to login next. There are some profile fields which don't require extra permissions, so it may not be required. However, most fields require some permissions, and in that case, the box will appear on the next login only. Each field has different types of permissions for 'basic' and 'extended' information. You'll have to test with the fields you want to import and the resulting login popup. Some fields can be skipped by the user, but still allow them to login your application/site, so it's not a horrible thing if you add a new popup later (the user can simply decline the new info).
Hope that explains,
Alex