Johnny,
So, if a user is on joomla.com, you want them to be redirected and registered on jomsocial.joomla.com? If you're using jFusion, that should just work, actually. While we don't test with jFusion specifically, we have many users who have successfully configured JFBConnect in multi-site / multi-database configurations.
We do recommend reading our Common Support Questions area, as one question is directly related to jFusion. The information provided there is from past users and has been verified by others:
www.sourcecoast.com/jfbconnect/docs/common-support-questions
Should you run into issues, let us know, and we'll do what we can to help!
Alex