For the redirect URL, put the address you want into the page below and you can get the Base64 version of it. There's plenty of tools in any language to do the same:
www.base64decode.com/
The Session token has to be generated by Joomla. So, the user will have to have a session opened in Joomla before the login attempt. To generate the token, use:
I hope that helps get you going.
Finally though, if you're not already, please make sure you're using JFBConnect v8. Facebook has made numerous changes over the last few months and features of older versions of JFBConnect aren't fully compatible with the recent updates. For more information, see our blog posts:
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Facebook's Recent Changes Due to Privacy Breaches
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JFBConnect v8 Changes and Updates Required for Your Site
Thanks,
Alex