There's quite a few different ways that existing users can add a social network to their account:
* Enable "Automatically link users by email" in the JFBConnect -> Configuration settings. When set, if a user authenticates with a social network and their email address on that network matches the account of an existing Joomla user, the accounts will be automatically linked together.
* If a user logs in with their Joomla account, the SCLogin module can be configured to show "Connect Account" buttons, like you can see in the "My Account" menu above (which is from SCLogin).
* Create a new JFBConnect -> Account menu item where a user can manage the social network connections they've made.
Beyond that, you can add our 'Connect Account' links anywhere using our EasyTag, like {JFBCLogin show_reconnect=true}. If you add that to your JomSocial user area, or any other place, the social networks that the user *hasn't* connected with already will show to allow them to do so.
I hope that helps, but if you need anything else, just let us know.
Thanks,
Alex