When responding to a request, certain data needs to go first, like cookies. The message indicates that JFBConnect is trying to set a cookie or otherwise sending some output to the browser. Then, later, another extension is also trying to output some data that needed to go first and it's complaining.
Normally, Joomla should take care of this ordering, so you shouldn't see that error. It's something we can gladly help you investigate further though.
Can you let us know what version of JFBConnect are you using? The latest is v8.4.6 for Joomla 3.x or the 9.0Beta which is compatible with both Joomla 3 and Joomla 4.
Thanks,
Alex