Steve,
I think your message got a little garbled some how. I think you want to be able to control the image that will display when you type your URL into Facebook. To do so, add the following tag to the page:
{JFBCGraph image=http://site.com/image-to-use.jpg}
That will set the image for the specific page it's set on. Additionally, if you'd like to set a default image for your entire site, you can add that in the Open Graph tab of the Social Configuration section of JFBConnect. In the defaults box, insert:
image=http://site.com/default-image-for-site.jpg
Once set, it will take Facebook up to 2 days to 'see' the new file. You can use the link below to check what Facebook will see though:
developers.facebook.com/tools/debug
Hope that helps,
Alex